Abstract:This paper based on the total solar radiation data from 1991~2023, the air quality monitoring data of Xi"an from 2014 to 2020 and the corresponding hourly radiation simulation data, defined the percentage of greater than 80% as a sunny day, introduced the solar radiation reduction, reduction rate and scattering coefficient, analyzed the interannual variation of solar radiation and the influence of ambient air quality on solar radiation. (1)There are good simulation effect of Simulation of total solar radiation, direct radiation, scattered radiation number used the first-generation Global Atmospheric Reanalysis 40-year product of China (CMA-RA), it can solve the problem of incomplete radiation observation projects at national stations.(2)Since 1991, the total solar radiation in the three different climatic regions of Shaanxi Province has shown a fluctuating increasing trend, and the spatial distribution of total solar radiation has increased from south to north.(3)Under sunny conditions, atmospheric pollution is one of the important factors affecting the solar radiation reaching the Earth"s surface. There are great difference of average total radiation between PM2.5 pollution days and non-pollution days,the radiation reduction amount, reduction ratet and scattering coefficien on polluted days are greater than those on clean days.On sunny days, latgest of reduction amount and reduction ratet occured in Ankang, respectively were 12.1MJ/m2 and 0.44, smallest in Xi "an respectively were 12.1MJ/m2 and 0.44. In addition, the average scattering coefficient of PM2.5 polluted day in Yan"an and Xi"an respectively was 0.50 and 0.39, while in Ankang was 0.23. It is consistent with that the ambient air quality of Xi "an and Yan "an is worse than that of Ankang, further verified that the scattering radiation increases due to the higher concentration of polluted particles.(4)Compared the relationship between pollutants and scattering coefficient in Xi "an on the same day or adjacent days, it can be seen that PM2.5 has a significant impact on solar radiation reduction when there is little difference in meteorological factors, the radiation reduction rate increases significantly with the increase of PM2.5 concentration.